Hydrogen peroxide (H₂O₂) is a chemical compound with a variety of uses and properties. Here are some key details:
Chemical Properties
Formula: H₂O₂
Molar Mass: 34.014 g/mol
Appearance: Very pale blue liquid
Odor: Slightly sharp
Density: 1.11 g/cm³ (20 °C, 30% solution), 1.450 g/cm³ (pure)
Melting Point: -0.43 °C
Boiling Point: 150.2 °C (decomposes)
Solubility: Miscible in water, soluble in ether and alcohol, insoluble in petroleum ether
Acidity (pKa): 11.75
Refractive Index: 1.4061
Viscosity: 1.245 cP (20 °C)
Dipole Moment: 2.26 D
Structure
Hydrogen peroxide has a non-planar, open-book structure with an O-O bond length of 145.8 pm and an O-H bond length of 98.8 pm. The dihedral angle between the planes containing the H-O-O group is 111°.
Preparation
Laboratory Method: Acidification of barium peroxide followed by evaporation under reduced pressure.
Industrial Method: Electrolysis of 30% ice-cold H₂SO₄, followed by hydrolysis of peroxodisulphate.
Uses
Oxidizer: Used in various chemical reactions as an oxidizing agent.
Bleaching Agent: Commonly used in the textile and paper industries.
Antiseptic: Used in dilute solutions (3%-6%) for cleaning wounds and disinfecting surfaces.
Propellant: Used in rocketry as a monopropellant and oxidizer.
Safety and Hazards
Hazard Statements: H271 (May cause fire or explosion; strong oxidizer), H302 (Harmful if swallowed), H314 (Causes severe skin burns and eye damage), H332 (Harmful if inhaled), H335 (May cause respiratory irritation), H412 (Harmful to aquatic life with long-lasting effects).
Precautionary Statements: P280 (Wear protective gloves/protective clothing/eye protection/face protection), P305+P351+P338 (IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing), P310 (Immediately call a POISON CENTER or doctor/physician).
Hydrogen peroxide is a versatile compound with many applications, but it must be handled with care due to its reactive nature.
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